Method and apparatus for capturing carbon dioxide during combustion of carbon containing fuel

ABSTRACT

A boiler system having a series of boilers. Each boiler includes a shell having an upstream end, a downstream end, and a hollow interior. The boilers also have an oxidizer inlet entering the hollow interior adjacent the upstream end of the shell and a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the hollow interior of the shell. Each boiler includes a flue duct connected to the shell adjacent the downstream end for transporting flue gas from the hollow interior. Oxygen is delivered to the oxidizer inlet of the first boiler in the series. Flue gas from the immediately preceding boiler in the series is delivered through the oxidizer inlet of each boiler subsequent to the first boiler in the series.

CROSS REFERENCE TO RELATED APPLICATION

This application claims priority to U.S. Provisional Patent Application No. 61/830,428, filed Jun. 3, 2013, which is hereby incorporated by reference in its entirety.

GOVERNMENT RIGHTS

This invention was made with government support under grant #DE-FE0009702 awarded by the Department of Energy. The government has certain rights in the invention.

BACKGROUND

The present invention generally relates to power generation, and more particularly, to a method and apparatus for reducing carbon dioxide (CO₂) when generating power from carbon-based fuels.

Most power generation is provided by heating a working fluid, such as water to produce steam, and using the heated fluid to turn a turbine connected to a generator, which produces electricity. A boiler is typically used to heat the working fluid. Conventional boilers burn fuel such as coal, producing a flame that heats working fluid flowing through tubes extending through the boiler. The heat energy transferred to the working fluid turns the turbine, which turns the generator connected to the turbine. The working fluid cools as it passes through the turbine. Frequently, the working fluid is directed back through the tubes in the boiler where it is reheated and used again to turn the turbine. Because carbon-based fuels are inexpensive relative to other heat sources, they are frequently used in the boiler. One drawback of using carbon-based fuels is they produce harmful emissions such as CO₂ when they burn.

One way of reducing CO₂ emissions from carbon-based power generation is oxy-combustion, in which fuel is burning in an environment of oxygen and recycled flue gas to produce high purity CO₂. In the past, oxy-combustion has been performed at atmospheric pressure and recycled flue gas was regulated to control flame temperature and heat transfer rate in the boiler yielding conditions similar to conventional air-fired boilers. Conventional oxy-combustion is costly and inefficient due to a need to produce oxygen for the process, as well as, a need to compress and purify emitted CO₂ before use or disposal.

To reduce cost and increase efficiency associated with capturing and pressurizing CO₂, some have suggested burning the fuel in a pressurized atmosphere. Prior pressurized oxy-combustion systems have heated the working fluid with flue gas using a convective heat exchanger (e.g., heat recover steam generator). The tubes in the heat exchanger carrying the working fluid are separated from the burning fuel so the working fluid is not radiantly heated by the flame. In these systems, flue gas is recycled to cool the flue gas entering the heat exchanger to prevent damage to the tubes due to excess gas temperatures. Recycling flue gas results in losses in power plant efficiency. Prior systems required recycled flue gas or inert gas in practice to prevent the heat exchanger from exceeding safe operating temperatures. Accordingly, there continues to be a need for an oxy-combustion system having increased efficiencies and lower operating costs.

SUMMARY

In one aspect, the present invention includes a boiler system. The system includes a series of boilers. Each boiler includes a generally cylindrical shell surrounding a vertical centerline. The shell defines an inner surface having an inner diameter and an inner length extending between an upper upstream end and a lower downstream end. The inner surface defines a hollow interior suitable for withstanding pressure greater than ambient. The interior has a pre-combustion zone, a combustion zone downstream from the pre-combustion zone, and a post-combustion zone downstream from the combustion zone. Each boiler includes an oxidizer inlet entering the pre-combustion zone of the hollow interior adjacent the upstream end of the shell. Each boiler also has a flow distributor mounted in the hollow interior of the shell downstream from oxidizer inlet adapted to provide oxidizer flowing downstream from the distributor with an even radial flow distribution, with an even circumferential flow distribution, and with a ratio of circular momentum to axial momentum of less than about 0.2. In addition, each boiler includes a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the combustion zone of the hollow interior of the shell along the centerline and downstream from the flow distributor. Further, each boiler has a flue duct connected to the shell adjacent the downstream end for transporting flue gas from the hollow interior. Oxygen is delivered to the first boiler in the series through the oxidizer inlet of the first boiler. Flue gas from the immediately preceding boiler in the series is delivered through the oxidizer inlet of each boiler subsequent to the first boiler in the series.

In another aspect, the present invention includes a boiler system having a series of boilers. Each of the boilers includes a shell having an upstream end, a downstream end opposite the upstream end, and a hollow interior. The boilers also have an oxidizer inlet entering the hollow interior adjacent the upstream end of the shell and a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the hollow interior of the shell. Each boiler has a flue duct connected to the shell adjacent the downstream end for transporting flue gas from the hollow interior. Oxygen is delivered to the oxidizer inlet of the first boiler in the series. Flue gas from the immediately preceding boiler in the series is delivered through the oxidizer inlet of each boiler subsequent to the first boiler in the series.

In still another aspect, the present invention includes a boiler having a generally cylindrical shell surrounding a vertical centerline. The shell defines an inner surface having an inner diameter and an inner length extending between an upper upstream end and a lower downstream end. The inner surface defines a hollow interior suitable for withstanding pressure greater than ambient. The interior has a pre-combustion zone, a combustion zone downstream from the pre-combustion zone, and a post-combustion zone downstream from the combustion zone. The boiler also includes an oxidizer inlet entering the pre-combustion zone of the hollow interior adjacent the upstream end of the shell. In addition, the boiler includes a flow distributor mounted in the hollow interior of the shell downstream from oxidizer inlet adapted to provide oxidizer flowing downstream from the distributor with an even radial flow distribution, with an even circumferential flow distribution, and with a ratio of circumferential momentum to axial momentum of less than about 0.2. The boiler has a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the combustion zone of the hollow interior of the shell along the centerline and downstream from the flow distributor. Further, the boiler includes a tube assembly mounted in the combustion zone and post-combustion zone of the hollow interior of the shell for transferring heat to fluid flowing through the assembly. The tube assembly has an upstream inner diameter surrounding the combustion zone and a downstream inner diameter surrounding the post-combustion zone. The downstream inner diameter is smaller than the upstream inner diameter. The boiler also has a flue duct connected to the shell adjacent the downstream end for transporting flue gases from the hollow interior.

In yet another aspect, the present invention includes a method of processing carbon-based byproducts when burning carbon-containing fuel. The method comprises cooling flue gas discharged from the final boiler in a series of pressurized boilers using boiler feed water to a temperature selected to prevent acid condensation. The cooled flue gas is filtered and fed into a top of a direct contact cooler at a rate selected to promote rate-limiting reactions. The method also includes introducing filtered flue gas through a bottom of the direct contact cooler to remove SO₂ and NO_(x) by conversion to dilute sulfuric and nitric acid.

In a final aspect, the present invention includes a method of reducing carbon-based byproducts when burning carbon-containing fuel. The method comprises introducing an oxidizer to an upstream boiler and introducing carbon-containing fuel to the upstream boiler. The oxidizer and carbon-containing fuel are burned in the upstream boiler. Flue gas emitted from the upstream boiler is transported to a downstream boiler. The method also includes introducing the flue gas to the downstream boiler for use as an oxidizer and introducing carbon-containing fuel to the downstream boiler. The flue gas and carbon-containing fuel are burned in the downstream boiler.

Other aspects of the present invention will be apparent in view of the following description and claims.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic of a system for heating working fluid of one embodiment.

FIG. 2 is a schematic of a vertical cross section of a working fluid heater of one embodiment.

FIG. 3 is a partial cross section taken in the plane of line 3-3 of FIG. 2.

FIG. 4 is a partial cross section taken in the plane of line 4-4 of FIG. 2.

FIG. 5 is a schematic of a working fluid cycle of one embodiment.

Corresponding reference characters indicate corresponding parts throughout the drawings.

DETAILED DESCRIPTION OF THE DRAWINGS

Referring to FIG. 1, a boiler system, more broadly a working fluid heater system, incorporating one embodiment of the present invention is designated in its entirety by the reference number 20. The system 20 includes a plurality of boilers, generally designated 22. In the illustrated system 20, four boilers 22 a-d are used. (System components are identified generally by number, and by number followed by an alphabetic character corresponding to its position in series when identified specifically.) Each boiler 22 includes a shell 24 having an oxidizer inlet 26 through which pressurized oxidizer enters the boiler and a fuel inlet 28 through which fuel enters the boiler. The mixture of oxidizer and fuel is burned in the boiler. A flue duct 30 connected to each boiler 22 allows discharge of flue gas resulting from combustion. Each boiler 22 also includes a working fluid inlet 32 and a working fluid outlet 34. Working fluid is discharged from the outlet 32 at a higher temperature than when entering the boiler 22 through the inlet 30. Working fluid enters each boiler 22 through its respective working fluid inlet 32 and exits each boiler 22 through its outlet 34 where it is directed to the steam cycle. Further, each boiler 22 has an ash discharge 36 through which bottom ash is removed from the boiler. The boilers 22 are joined in series so that flue gas from the immediately upstream boiler enters the oxidizer inlet 26 of each boiler downstream from the first boiler. Thus, oxygen (O₂) is used as a principle component of an oxidizer in the first boiler 22 a in the series, but flue gas from the immediately upstream boiler is used as the oxidizer in each subsequent boiler 22 b-d. For example, flue gas from boiler 22 b is directed to the oxidizer inlet 26 c of boiler 22 c. Although all the oxygen is delivered to the first boiler 22 a in the described embodiment, some oxygen may be needed in the other boilers for flame stabilization. In general, each boiler may have multiple inlet ports to allow the injection of other gases, for example recycled flue gas to control temperature or heat transfer rate.

Although other technology may be used, in one embodiment air A is directed to an air separation unit having a main air compressor 40 and a cold distillation box 42, which separates oxygen from other air components. In the described embodiment, nearly pure oxygen exiting the separation unit 42 is directed through a second compressor 44 before being directed to the oxidizer inlet 26 a of the first boiler 22 a. In another embodiment, an alternative air separation unit incorporating pumped liquid oxygen may be used, in which case oxygen leaving the cold distillation box 42 is pressurized and a second compressor 44 is not required. In the first described embodiment, residual air components (i.e., mostly nitrogen (N₂)) exit the separation unit 42 and are directed to a conventional cooling tower 46. Heat exchangers or economizers 48, 50 are provided between the main air compressor 40 and the air separation unit 42. Boiler feed water, more broadly working fluid, WF passes through the first heat exchanger 48 where is heated by the compressed air for use in the steam cycle 52. Some of the residual air components are directed through the second heat exchange 50 for use in coal milling. Other technologies for producing O₂, such as membrane air separation, may also be used without departing from the scope of the present invention. As will be appreciated by those skilled in the art, using nearly pure O₂ in the boilers 22 and eliminating N₂ and other residual air components, the flue gas is primarily CO₂ after the O₂ is burned in the last boiler 22 d and residual water and remaining contaminants are removed.

Coal, more broadly fuel, C enters a coal milling unit 60 where it is pulverized to a predetermined size for use in the boilers 22 a-d. In the described embodiment, the residual air components directed to the coal milling unit 60 from the air separation unit 42 are used by the milling unit as will be understood by those skilled in the art. Coal exiting the milling unit 60 is directed to coal feeding unit 62 which feeds a predetermined amount of milled coal to each fuel inlet 28 a-d of the boilers 22 a-d. The air components used by the milling unit 60 are exhausted through a vent 64. Although other flow rates of milled coal C may be delivered to the boilers 22 without departing from the scope of the present invention, in one embodiment, about 17.4 kg/s of milled coal is delivered through the fuel nozzle 106 of the first boiler 22 a and about 20.52 kg/s of milled coal is delivered through the fuel nozzles of each subsequent boiler 22 b-22 d in the series. Although fuel may be delivered to the boilers using other means, in one embodiment the feeding unit 62 is a pneumatic dry feeder using a small amount of recycled flue gas as motive gas. Other feeding techniques, such as a dry solids pump, which are capable of delivering dry coal at up to 40 bar without motive gas and slurry feed may also be used without departing from the scope of the present invention.

Flue gas discharged from the final boiler in the series 22 d, is directed to a heat exchanger 70 where it is cooled using boiler feed water WF. Although other types of heat exchangers may be used, in one embodiment the heat exchanger 70 is a convective heat exchanger. The resulting heated boiler feed water WF is directed to the steam cycle, and the cooled flue gas is directed to a particulate filter 72 and then to a direct contact cooler or condenser 74 where the flue gas is scrubbed to remove sulfur oxides (SOx) and other contaminants. The temperature of the flue gas exiting the heat exchanger 70 may be selected to prevent acid condensation downstream. The particulate filter 72 (e.g., a candle filter) separates fly ash F from the flue gas. Both cooling and moisture condensation occur in the direct contact cooler 74. Cooling water flows through the cooler 74 from the top, and flue gas from the bottom. The cooler performs a dual role. The first is to cool and condense the moisture from the flue gas, which occurs in the bottom stages. The second is to remove SO_(x) and NO_(x), via conversion to dilute sulfuric and nitric acid, which is performed in the top stages. The system 20 is expected to remove almost all of the SO₂ and NO_(x) as the boilers 22 can produce higher NO_(x) than in a conventional oxy-combustion system (due to the high local flame temperatures) and hence has a lower SO_(x)/NO_(x) ratio, which is believed to provide higher efficiency SO_(x) and NO_(x) removal. Mercury present in the flue gas can also be removed in the same cooler 74 either via dissolution or reaction. Although multiple columns may be used without departing from the scope of the present invention, in one embodiment the cooler 74 is formed as a single column to minimize equipment exposed to corroding acids. Further, the flow rates of the liquid in the column and the column height may be adjusted to allow the top stages of the cooler 74 to be at low temperature, promoting the overall rate-limiting reaction, while allowing most of the cooling and condensation to occur in the bottom stages. Among the advantages of this cooler 74 over others are: 1) the capture of SOx and NOx simultaneously, which is more economical as compared to separate removal process such as selective catalytic reduction (SCR) for NOx removal and sorbent injection for SO2; 2) large pieces of equipment are eliminated, resulting in significant capital cost savings; and 3) acid gas condensation is controlled to occur only in one column, eliminating the chances of corrosion in other parts of the system.

The contaminants scrubbed from the flue gas by the cooler 74 are directed to a neutralizer 76, which uses caustic or other neutralizing agents to adjust acidity of the contaminants, before being directed to a heat exchanger 78 for further cooling. The cooling water used in the direct contact cooler 74 for cooling and condensation exits the bottom of the cooler at relatively high temperature (e.g., about 165° C.) with some acid concentration (e.g., about 730-4000 ppmv. After neutralization, the water is passed through a heat exchanger (e.g., an indirect heat exchanger) for regeneration of low temperature fluid. This heat, in conjunction with the low-grade heat that is available from the air separation unit 42, greatly reduces or eliminates (depending on the fuel) the need for steam extraction from a low pressure turbine in the steam cycle, allowing for higher gross power generation.

The cooled contaminants are directed to the cooling tower 46. Boiler feed water WF passing through the heat exchanger is heated and directed to the steam cycle. The direct contact cooler 74 is connected to cooling water CW for condensing the flue gas. The treated flue gas is directed through a compressor 80 before being recycled through the coal feeding unit 62 and onward to the fuel inlets 28 of the boilers 22. Some of the flue gas passes through a heat exchanger 82 where it is cooled with cooling water CW. The cooling water CW is discharged to the cooling tower 46, and the cooled flue gas is directed to a compression and purification unit 84. Purified fluid gas exhausts through a vent 86 in the purification unit 84, and contaminant residues are directed to sequestration area 88. Although the unit 84 may be selected to operate at other pressures, in one embodiment the unit 84 operates at a pressure of about 35 bar. A small fraction (e.g., about 3-5%) of this compressed, dry flue gas is recycled back for carrying the coal in a dense phase. The majority (e.g., >95 vol %) is sent to the unit after passing through molecular sieves (not shown) for further moisture removal, and a bed of an activated carbon (not shown) for removal of residual mercury in the gas. The purification unit 84 in one embodiment uses cryogenic distillation to purify the CO₂ to the desired specification. In one embodiment, an auto-refrigeration unit 84 is used.

Only a small fraction of the flue gas is recycled through the boilers 22. In general, eliminating flue gas recycle results in a dramatic increase in temperature of the combustion products and the rate of radiant heat transfer, as compared to combustion in air. In some instances, the resulting temperatures and heat transfer can damage boiler tubes. As will be appreciated by those skilled in the art, these damaging temperatures and heat transfer rates are avoided by using a plurality of boilers in series, staging fuel delivery, and controlling mixing of fuel and oxidizer in the boilers.

In a conventional boiler, slightly more (e.g., about 15%) oxygen is supplied than required to completely burn the fuel. In the multi-boiler system described above, the first boiler 22 a in the series is over-supplied with oxygen to achieve a stoichiometric ratio (i.e., the ratio of O₂ supplied to O₂ needed for complete combustion) of about 4. The excess O₂ acts as a diluent that reduces the temperature of the combustion products and heat transfer. Heat is extracted from the first boiler 22 a and is transferred to the steam cycle where the flue gas temperature is reduced. The products of combustion from the first boiler 22 a, including the excess O₂, are directed to the second boiler 22 b where additional fuel is injected and more O₂ is consumed. This process continues in the third and fourth boilers 22 c, 22 d until nearly all of the O₂ is consumed. Rather than supplying all the fuel to one boiler, part of the fuel is supplied to each boiler in the series. The total gas flow rate in this process is equivalent to a boiler in which only enough oxygen to burn the fuel is used. When multiple boilers in series are used, dilution is available in a local sense in each boiler to control temperatures and heat transfer. As a result, the amount of heat transfer may be increased while maintaining the temperatures at acceptable levels.

As illustrated in FIG. 2, a boiler, more broadly a working fluid heater, incorporating a first embodiment of the present invention is designated in its entirety by the reference number 22. This boiler is representative of the plurality of boilers 22 joined in series in FIG. 1. As further shown in FIG. 2, the boiler 22 includes an elongate cylindrical shell 90 surrounding a vertical centerline L. The shell 90 has an inner surface 92 having an inner diameter and an inner length extending between an upper upstream end 96 and a lower downstream end 98. Although the inner diameter and length of the shell may vary without departing from the scope of the present invention, in one embodiment the shell has an inner diameter of about 13 ft to about 15 ft and a length of about 240 ft. Further, in one embodiment, the diameter tapers from about 15 ft at the upper end 96 to about 13 feet at the lower end 98. The inner surface 92 of the shell 90 defines a hollow interior 100 having a pre-combustion zone Z₁, a combustion zone Z₂ downstream from the pre-combustion zone, and a post-combustion zone Z₃ downstream from the combustion zone. The shell 90 forms a pressure vessel capable of withstanding anticipated pressures achieved in the process. An oxidizer inlet 102 enters the pre-combustion zone Z₁ of the hollow interior 100 adjacent the upstream end 96 of the shell 90. A flow distributor 104 is mounted in the hollow interior 100 of the shell 90 downstream from the oxidizer inlet 102. The flow distributor 104 is selected to provide a sufficiently high pressure drop that oxidizer downstream from the distributor has an even radial flow distribution, an even circumferential flow distribution, and a ratio of circular momentum to axial momentum of less than about 0.2. The shell 90 also has a fuel nozzle 106 positioned adjacent the upstream end 96 for introducing fuel into the combustion zone Z₂ of the hollow interior 100 of the shell along the centerline L and downstream from the flow distributor 104. The fuel injected into the interior 100 through the nozzle 106 along the center axis and the low mixing between the oxidizer and fuel creates a long combustion zone Z₂ and a thin flame, which reduces heat transfer rates at the shell 90. An outlet 108 leading to a flue duct 30 (FIG. 1) is provided in the side of the shell 90 adjacent the downstream end 98 for transporting flue gas from the hollow interior 100. An ash and condensate trap 110 is provided at the bottom of the boiler 22 for collecting bottom ash and water.

As illustrated in FIGS. 2-4, the boiler 22 has several tube assemblies 120-130 comprising tubes extending axially with respect to the centerline L. The tube assemblies 120-130 are mounted in the combustion zone Z₂ and post-combustion zone Z₃ of the hollow interior 100 of the shell 90 for transferring heat primarily by radiation heat transfer from combusting fuel adjacent the centerline L to working fluid flowing through the assemblies. Tube assemblies 120 and 122 extend from the flow distributor 104, through the combustion zone Z₂ to absorb radiant heat provided by flame in the combustion zone and shield the shell 90 from the flame. These tube assemblies 120, 122 extend into the post-combustion zone Z₃, to supplement heat transfer provided by tubes 124-130, which extend through the post-combustion zone Z₃. In order to prevent the tubes in tube assemblies 120 and 122 from overheating, they are positioned at larger diameters than the other tube assemblies 124-130. For example, in one embodiment tube assembly 120 is positioned at a diameter of about 14.9 ft, tube assembly 122 is positioned at about 13 ft, tube assembly 124 is positioned at about 10.6 ft, tube assembly 126 is positioned at about 8.2 ft, tube assembly 128 is positioned about 5.6 ft, and tube assembly 130 is positioned at about 3 ft. Further, the tubes 120-130 are positioned in the shell 90 with their upstream ends at different axial locations with respect to the flow distributor 104. For example, in the aforementioned embodiment tube assemblies 120 and 122 have upstream ends that are positioned upstream from the flow distributor 104, the upstream end of tube assembly 124 is positioned at about 175 ft downstream from the flow distributor, tube assembly 126 is positioned at about 185 ft, tube assembly 128 is positioned about 195 ft, and tube assembly 130 is positioned at about 205 ft. The tube assemblies 120-130 also have different lengths. In the same embodiment, tube assembly 120 is about 237 ft long, assembly 122 is about 198 ft, assembly 124 is about 23 ft, tube assembly 126 is about 41 ft, tube assembly 128 is about 55 ft, and tube assembly 130 is about 62 ft.

Tube assembly 120 has an inlet 120, at its downstream end and an outlet 120 _(o) at its upstream end. Cooling water CW is transported the tube assembly 120 to form a tube liner that shields the shell 90 from heat generated by the burning fuel. In one embodiment, the cooling water CW remains at a temperature below about 294° C. at the outlet 120 _(o) to prevent damage to the shell 90. Each assembly 122-130 is divided into an upstream or superheater portion 122 _(u)-130 _(u), respectively, and a downstream or reheater portion 122 _(d)-130 _(d), respectively. Each upstream portion 122 _(u)-130 _(u) forms a superheater unit having an inlet 122 _(ui)-130 _(ui), respectively, at its downstream end and an outlet 122 _(uo)-130 _(uo), respectively, at its upstream end. Each downstream portion 122 _(d)-130 _(d), forms a reheater unit having an inlet 122 _(di)-130 _(di), respectively, at its upstream end and an outlet 122 _(do)-130 _(do), respectively, at its downstream end. As will be appreciated by those skilled in the art, the positions of the various tube assembly inlets 120 _(i), 122 _(ui)-130 _(ui), 122 _(di)-130 _(di) and outlets 120 _(o), 122 _(uo)-130 _(uo), 122 _(do)-130 _(do) are selected so the assemblies 120-130 provide working fluid of a selected temperature. For example, in the previously mentioned embodiment, the fluid entering tube assembly inlet 122 _(ui) is about 294° C. and is heated so it exits the upper portion tube assembly outlet 122 _(uo) at about 384° C. Fluid entering the remaining upstream portions of the tube assembly inlets 124 _(ui-) 130 _(ui) at about 384° C. and is heated so it exits the corresponding tube assembly outlets 124 _(uo-) 130 _(uo) at about 593° C. Similarly, fluid entering tube assembly inlet 122 _(di) is about 384° C. and is heated so it exits the upstream portion tube assembly outlet 122 _(do) at about 593° C. Fluid entering the remaining downstream portions of the tube assembly inlets 124 _(di-) 130 _(di) at about 352° C. and is heated so it exits the corresponding tube assembly outlets 124 _(do-) 130 _(do) at about 593° C. The various fluid temperatures are selected to provide working fluid at advantageous temperatures for use in other parts of the system as explained below.

As shown in FIG. 5, the steam cycle 58 includes one or more turbines having a governing stage 140, a high pressure stage 142, an intermediate pressure stage 144, and a low pressure stage. Working fluid is directed from the outlets of the upstream portions of tube assemblies 122 _(uo)-130 _(uo) to the governing stage 140 and onward to the high pressure stage 142. The high pressure stage 142 feeds steam to the intermediate stage 144. Steam exiting the intermediate stage 144 is directed to the inlets of the downstream portions of tube assemblies 122 _(di)-130 _(di) for reheating before returning to the low pressure stage 146. After exiting the low pressure stage 146 of the turbine, the working fluid is directed to a condenser 148. Although other condensers may be used, in one embodiment, the condenser 148 is selected to have a pressure of 0.048 bar and a terminal temperature difference of 11.7° C. A pump 150 is provided for pumping fluid from the condenser 148. The fluid is pumped to the heat exchanger 78 and used as the cooling water CW for condensing the flue gas with the heat exchanger 82 as previously explained. The fluid is also pumped to intercoolers in the main air compressor 40, the oxygen air compressor 44, and a booster air compressor 152.

As further illustrated in FIG. 5, working fluid is bled from the intermediate stage 144. This fluid passes through a deaerator 154 to remove oxygen and other dissolved gases from the fluid. Used cooling fluid from the heat exchanger 78, and the intercoolers in the main air compressor 40, the oxygen air compressor 44, and the booster air compressor 152 are also fed through the deaerator 154. A pump 156 is provided for pumping fluid from the deaerator 154 through heat exchangers 156, 160, 70, sequentially, and on to the inlets of the upstream tube assemblies 122 ui-130 ui. Fluid in these tube assemblies is heated and returned from the outlets of the upstream portions of tube assemblies 122 _(uo)-130 _(uo) to the governing stage 140. Fluid bled from the high pressure stage 142 is directed through heat exchangers 158, 160 to heat the fluid before reaching the heat exchanger 70. The bleed fluid passing through heat exchanger 160 is mixed with bleed fluid entering heat exchanger 158, and the bleed fluid exiting the heat exchanger 158 is directed to the deaerator 154 where it mixes with the other fluid entering the deaerator. As will be apparent to those skilled in the art, heat generated from the compression of air is integrated with the steam cycle and used for boiler feed water regeneration.

The system 20 described above is used to heat working fluid by burning carbon-containing fuel in pressurized boilers or working fluid heaters 22. An oxidizer (e.g., O₂, or O₂ and flue gas) and carbon-containing fuel is introduced to an upstream boiler (e.g., 22 a or 22 b) The oxidizer and carbon-containing fuel is burned in the upstream boiler, and the flue gas emitted from the upstream boiler is transported to a downstream boiler (e.g., 22 b or 22 c). The flue gas is introduced to the downstream boiler for use as an oxidizer. Carbon-containing fuel is introduced to the downstream boiler, and the flue gas and carbon-containing fuel are burned in the downstream boiler. The oxidizer is introduced into the respective boiler through a flow distributor 104 so the oxidizer enters the boiler with circumferentially and axially even distributions. The distributor 104 further ensures the oxidizer has a ratio of circular momentum to axial momentum of less than about 0.2. Heat exchangers 122-130 are provided in each boiler 22 to heat working fluid by passing it through the heat exchanger when burning the oxidizer and carbon-containing fuel. In some embodiments, heat exchangers 124-130 are divided so they provide a superheater unit and a reheater unit.

The system uses an air separation unit 42 for separating oxygen from air. The separated oxygen is delivered to the upstream boiler (e.g., boiler 22 a) for use as the oxidizer. Although other flow rates of oxygen may be delivered without departing from the scope of the present invention, in one embodiment about 120 kg/s of oxygen are delivered through the oxidizer inlet 102 into the hollow interior 100 of the shell 90 of the first boiler 22 a in the series. After the flue gas is emitted from the final boiler, it is filtered to separate fly ash from the flue gas. The filtered flue gas is scrubbed by the direct contact cooler 74 to remove sulphur oxides and nitrogen oxides. The cooler 74 also cools the flue gas.

The portion of the system shown in FIG. 5 expands working fluid emitted by each boiler 22 with a multi-stage turbine. Working fluid from the superheater unit is delivered to the highest pressure stage (e.g., governing stage 140). Working fluid emitted from an intermediate stage (e.g., stage 144) is delivered to the reheater unit. Once heated by the reheater unit, the working fluid is delivered to a lower pressure stage (e.g., stage 146) where the fluid is expanded. Fluid leaving the lowest pressure stage (e.g., stage 146) is delivered to one or more heat exchangers where it is heated and returned to the boilers 22 for heating.

Several variables should be considered when selecting the boiler operating pressures. First, flue gas moisture condensation as a function of pressure and temperature should be considered. Second, the pressure needed for effective removal of SO₂ and NO_(x). Third, in order to transfer most of the heat extracted at the direct contact cooler 76 to the cold boiler feed water for regeneration while maintaining the minimum approach temperature in the regenerator, the pressure should be high enough to transfer the heat to the boiler feed water without violating the minimum temperature approach. Fourth, fluid mechanics should also be considered. As these considerations are well within the skill of the ordinary artisan, they will not be discussed in detail.

The process described above uses combustion of carbon-based fuels (e.g., coal) for supplying high temperature and pressure working fluid (e.g., steam) for generating power. Carbon dioxide (CO₂) produced during the process is captured and prevented from being emitted to the atmosphere.

For more information concerning the system and process described above, reference may be made to Axelbaum, et al., “Process Design and Performance Analysis of a Staged, Pressurized Oxy-Combustion (SPOC) Power Plant for Carbon Capture”, Applied Energy, volume ______, (______2014), and Axelbaum, et al., “Phase I Topical Report: Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up”, DOE Award Number DE-FE0009702 (issued Jun. 28, 2013), both of which are hereby incorporated by reference.

The system 20 and process described above provide several advantages. Fuel staging allows a large degree of control over radiative heat transfer in the boiler. By controlling the mixing and the local ratios of fuel and oxygen, the combustion temperature and radiation can be manipulated. Furthermore, by introducing the fuel in stages, the overall length of the radiative section can be lengthened, allowing more heat to be transferred by radiation, as opposed to convection. Because the rate of heat transfer is higher for radiation than convection, staged combustion minimizes the required boiler tube surface area, reducing capital costs. In addition, fuel staging allows increased control over radiative heat transfer in the boiler. By controlling the mixing and the local ratios of fuel and oxygen, the combustion temperature and radiation can be manipulated. Furthermore, by introducing the fuel in stages, the overall length of the radiative section can be increased.

The system 20 and process described above produces high local temperature but controlled heat transfer rates, potentially leading to higher levels of NOx and thus a more effective process for combined SO_(x) and NO_(x) removal. This increases efficiency and significantly reduces capital costs over scrubbing approaches for SOx removal.

Eliminating flue gas recycle potentially reduces the size of the boilers, pumps, and other equipment. Heat loss to the ambient is also reduced. Importantly, the volume of gas undergoing treatment for removal of ash and other contaminants is reduced, and the concentrations of these contaminants is increased, making their removal easier and more cost effective. Further, flue gas recirculation accounts for a significant amount of parasitic power demand (about 3.5-5% of the plant electrical output) in conventional pressurized oxy-fuel systems. By eliminating recycled flue gas, losses associated with recycle and the equipment for transporting the recycled gas are avoided. Thus, efficiencies are higher and capital costs are lower.

Some low rank fuels, such as lignite, have limited use due to their very high moisture content, making them difficult to ignite or combust in air because moisture evaporation lowers flame temperature and delays volatile release. Using pure oxygen results in a higher flame temperature near the burner and improved stability, making low rank fuels easier to burn. Further, since much of the latent heat in the flue gas can be captured in pressurized combustion, the effective heating value of “low-Btu” fuels can be significantly increased.

In brief, the primary benefits of pressurized oxy-combustion include: 1) The moisture in the flue gas condenses at higher temperature, and thus the latent heat of condensation can be utilized to improve the overall cycle efficiency; 2) the gas volume is greatly reduced, therefore the size and cost of equipment can be reduced; 3) air ingress, which normally occurs in induced-draft systems, is avoided, thereby increasing the CO2 concentration of the combustion products and reducing purification costs; and 4) at higher pressure, the convective heat transfer to boiler tubes is increased, for a given mean velocity. This is due to the increase in flue gas density with pressure, and therefore increased Reynolds number and convective heat transfer coefficient.

Having described the invention in detail, it will be apparent that modifications and variations are possible without departing from the scope of the invention defined in the appended claims.

When introducing elements of the present invention or the preferred embodiment(s) thereof, the articles “a”, “an”, “the”, and “said” are intended to mean that there are one or more of the elements. The terms “comprising”, “including”, and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements.

As various changes could be made in the above constructions, products, and methods without departing from the scope of the invention, it is intended that all matter contained in the above description and shown in the accompanying drawings shall be interpreted as illustrative and not in a limiting sense. 

What is claimed is:
 1. A boiler system, comprising: a series of boilers, each of said boilers including: a generally cylindrical shell surrounding a vertical centerline, the shell defining an inner surface having an inner diameter and an inner length extending between an upper upstream end and a lower downstream end, said inner surface defining a hollow interior suitable for withstanding pressure greater than ambient, the interior having a pre-combustion zone, a combustion zone downstream from the pre-combustion zone, and a post-combustion zone downstream from the combustion zone; an oxidizer inlet entering the pre-combustion zone of the hollow interior adjacent the upstream end of the shell; a flow distributor mounted in the hollow interior of the shell downstream from oxidizer inlet adapted to provide oxidizer flowing downstream from the distributor with an even radial flow distribution, with an even circumferential flow distribution, and with a ratio of circular momentum to axial momentum of less than about 0.2; a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the combustion zone of the hollow interior of the shell along the centerline and downstream from the flow distributor; and a flue duct connected to the shell adjacent the downstream end for transporting flue gas from the hollow interior; wherein oxygen is delivered to the first boiler in the series through the oxidizer inlet of said first boiler; and wherein flue gas from the immediately preceding boiler in the series is delivered through the oxidizer inlet of each boiler subsequent to said first boiler in the series.
 2. A boiler system as set forth in claim 1, wherein each boiler further comprises a tube assembly mounted in the combustion zone and post-combustion zone of the hollow interior of the shell for transferring heat to fluid flowing through the assembly, the assembly having an upstream inner diameter surrounding the combustion zone and a downstream inner diameter surrounding the post-combustion zone, the downstream inner diameter being smaller than the upstream inner diameter.
 3. A boiler system as set forth in claim 2, wherein: the tube assembly of each boiler in the series comprises a first group of tubes and a second group of tubes; each tube of the first group of tubes includes an upstream portion and a downstream portion, each upstream portion of the first group having an inlet at a downstream end of the upstream portion and an outlet at an upstream end of the upstream portion, each downstream portion of the first group comprising a superheater unit having an inlet at an upstream end of the downstream portion and an outlet at a downstream end of the downstream portion; and each tube of the second group of tubes includes an upstream portion and a downstream portion, each upstream portion of the second group comprising a superheater unit having an inlet at an upstream end of the upstream portion and an outlet at a downstream end of the upstream portion, each downstream portion of the second group comprising a reheater unit having an inlet at an upstream end of the downstream portion and an outlet at a downstream end of the downstream portion.
 4. A boiler system as set forth in claim 3, wherein: each boiler of said series is operatively connected to a plurality of turbines; fluid from the outlet of the superheater units is delivered to a first turbine of said plurality of turbines; fluid from the first turbine is delivered to the inlet of the reheater unit of each boiler in the series; fluid from the reheater unit of each boiler in the series is delivered to a second turbine of said plurality of turbines; and fluid from the second turbine is delivered to the inlet of the upstream portion of the first group of tubes of each boiler in the series.
 5. A boiler system as set forth in claim 1, wherein each boiler further comprises a tube liner lining the shell for transporting coolant inside the inner surface of the shell to cool the shell.
 6. A boiler system as set forth in claim 1, wherein flue gas from the final boiler in the series is mixed with fuel introduced through the fuel nozzle of each boiler in the series of boilers.
 7. A boiler system as set forth in claim 1, further comprising an air separator adapted to separate oxygen from air, said separated oxygen being delivered to the oxidizer inlet of the first boiler in the series.
 8. A boiler system as set forth in claim 1, further comprising a filter adapted to separate fly ash from flue gas emitted by the final boiler in the series.
 9. A boiler system as set forth in claim 1, further comprising a cooler adapted to cool flue gas emitted by the final boiler in the series.
 10. A boiler system as set forth in claim 1, further comprising a scrubber adapted to remove sulphur oxides from flue gas emitted by the final boiler in the series.
 11. A boiler system, comprising: a series of boilers, each of said boilers including: a shell having an upstream end, a downstream end opposite said upstream end, and a hollow interior; an oxidizer inlet entering the hollow interior adjacent the upstream end of the shell; a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the hollow interior of the shell; and a flue duct connected to the shell adjacent the downstream end for transporting flue gas from the hollow interior; wherein oxygen is delivered to the oxidizer inlet of the first boiler in the series; and wherein flue gas from the immediately preceding boiler in the series is delivered through the oxidizer inlet of each boiler subsequent to said first boiler in the series.
 12. A boiler system as set forth in claim 11, wherein each boiler in the series further comprises a flow distributor mounted in the hollow interior of the shell downstream from oxidizer inlet adapted to provide oxidizer flowing downstream from the distributor with an even radial flow distribution, with an even circumferential flow distribution, and with a ratio of circular momentum to axial momentum of less than about 0.2.
 13. A boiler system as set forth in claim 11, wherein each boiler in the series further comprises a tube assembly mounted in the hollow interior of the shell for transferring heat to fluid flowing through the tube assembly.
 14. A boiler system as set forth in claim 13, wherein the tube assembly of each boiler in the series has an upstream inner diameter and a downstream inner diameter, the downstream inner diameter being smaller than the upstream inner diameter.
 15. A boiler system as set forth in claim 14, wherein: the tube assembly of each boiler in the series comprises a first group of tubes and a second group of tubes; each tube of the first group of tubes includes an upstream portion and a downstream portion, each upstream portion of the first group having an inlet at a downstream end of the upstream portion and an outlet at an upstream end of the upstream portion, each downstream portion of the first group comprising a superheater unit having an inlet at an upstream end of the downstream portion and an outlet at a downstream end of the downstream portion; and each tube of the second group of tubes includes an upstream portion and a downstream portion, each upstream portion of the second group comprising a superheater unit having an inlet at an upstream end of the upstream portion and an outlet at a downstream end of the upstream portion, each downstream portion of the second group comprising a reheater unit having an inlet at an upstream end of the downstream portion and an outlet at a downstream end of the downstream portion.
 16. A boiler system as set forth in claim 15, wherein: each boiler of said series is operatively connected to a plurality of turbines; fluid from the outlet of the superheater units is delivered to a first turbine of said plurality of turbines; fluid from the first turbine is delivered to the inlet of the reheater unit of each boiler in the series; fluid from the reheater unit of each boiler in the series is delivered to a second turbine of said plurality of turbines; and fluid from the second turbine is delivered to the inlet of the upstream portion of the first group of tubes of each boiler in the series.
 17. A boiler system as set forth in claim 11, wherein flue gas from the final boiler in the series is mixed with fuel introduced through the fuel nozzle of each boiler in the series of boilers.
 18. A boiler system as set forth in claim 11, further comprising an air separator adapted to separate oxygen from air, said separated oxygen being delivered to the oxidizer inlet of the first boiler in the series.
 19. A boiler system as set forth in claim 11, further comprising a filter adapted to separate fly ash from flue gas emitted by the final boiler in the series.
 20. A boiler system as set forth in claim 11, further comprising a cooler adapted to cool flue gas emitted by the final boiler in the series.
 21. A boiler system as set forth in claim 11, further comprising a scrubber adapted to remove sulphur oxides from flue gas emitted by the final boiler in the series.
 22. A boiler, comprising: a generally cylindrical shell surrounding a vertical centerline, the shell defining an inner surface having an inner diameter and an inner length extending between an upper upstream end and a lower downstream end, said inner surface defining a hollow interior suitable for withstanding pressure greater than ambient, the interior having a pre-combustion zone, a combustion zone downstream from the pre-combustion zone, and a post-combustion zone downstream from the combustion zone; an oxidizer inlet entering the pre-combustion zone of the hollow interior adjacent the upstream end of the shell; a flow distributor mounted in the hollow interior of the shell downstream from oxidizer inlet adapted to provide oxidizer flowing downstream from the distributor with an even radial flow distribution, with an even circumferential flow distribution, and with a ratio of circumferential momentum to axial momentum of less than about 0.2; a fuel nozzle positioned adjacent the upstream end of the shell for introducing fuel into the combustion zone of the hollow interior of the shell along the centerline and downstream from the flow distributor; a tube assembly mounted in the combustion zone and post-combustion zone of the hollow interior of the shell for transferring heat to fluid flowing through the assembly, the tube assembly having an upstream inner diameter surrounding the combustion zone and a downstream inner diameter surrounding the post-combustion zone, the downstream inner diameter being smaller than the upstream inner diameter; and a flue duct connected to the shell adjacent the downstream end for transporting flue gases from the hollow interior.
 23. A boiler as set forth in claim 22, further comprising a shield assembly mounted on the shell for providing coolant along the inner surface of the shell.
 24. A boiler as set forth in claim 23, wherein the shield assembly comprises a plurality of tubes extending axially with respect to the centerline and adjacent the inner surface of the shell, said tubes being adapted for carrying coolant to cool the inner surface of the shell.
 25. A boiler as set forth in claim 22, wherein the tube assembly comprises a plurality of tubes extending axially with respect to the centerline, said tubes being adapted for carrying fluid and for transferring heat from combusting fuel adjacent the centerline to the fluid in the plurality of tubes.
 26. A boiler as set forth in claim 22, wherein said plurality of tubes an upstream portion and a downstream portion, each upstream portion comprising a superheater unit having an inlet at an upstream end of the upstream portion and an outlet at a downstream end of the upstream portion, each downstream portion comprising a reheater unit having an inlet at an upstream end of the downstream portion and an outlet at a downstream end of the downstream portion.
 27. A method of processing carbon-based byproducts when burning carbon-containing fuel, said method comprising: cooling flue gas discharged from the final boiler in a series of pressurized boilers using boiler feed water to a temperature selected to prevent acid condensation; filtering the cooled flue gas; feeding cooling water into a top of a direct contact cooler at a rate selected to promote rate-limiting reactions; and introducing filtered flue gas through a bottom of the direct contact cooler to remove SO₂ and NO_(x) by conversion to dilute sulfuric and nitric acid.
 28. A method of reducing carbon-based byproducts when burning carbon-containing fuel, said method comprising: introducing an oxidizer to an upstream boiler; introducing carbon-containing fuel to the upstream boiler; burning the oxidizer and carbon-containing fuel in the upstream boiler; transporting flue gas emitted from the upstream boiler to a downstream boiler; introducing the flue gas to the downstream boiler for use as an oxidizer; introducing carbon-containing fuel to the downstream boiler; and burning the flue gas and carbon-containing fuel in the downstream boiler.
 29. A method as set forth in claim 28, wherein: the upstream boiler is a first boiler; the downstream boiler is a second boiler; and the method further comprises: transporting flue gas emitted from the second boiler to a third boiler; introducing the flue gas from the second boiler to the third boiler for use as an oxidizer; introducing carbon-containing fuel to the third boiler; and burning the flue gas and carbon-containing fuel in the third boiler.
 30. A method as set forth in claim 29, further comprising: transporting flue gas emitted from the third boiler to a fourth boiler; introducing the flue gas from the third boiler to the fourth boiler for use as an oxidizer; introducing carbon-containing fuel to the fourth boiler; and burning the flue gas and carbon-containing fuel in the fourth boiler.
 31. A method as set forth in claim 28, wherein each of the steps of introducing oxidizer comprises providing a circumferentially and axially even distribution of oxidizer in the respective boiler.
 32. A method as set forth in claim 28, wherein each of the steps of introducing oxidizer comprises ensuring the oxidizer has a ratio of circular momentum to axial momentum of less than about 0.2.
 33. A method as set forth in claim 28, further comprising: providing a heat exchanger in each of said boilers; and passing a fluid through the heat exchanger when burning the oxidizer and carbon-containing fuel thereby to heat said fluid.
 34. A method as set forth in claim 33, further comprising: providing the heat exchanger with a superheater unit; and providing the heat exchanger with a reheater unit.
 35. A method as set forth in claim 34, further comprising: expanding flue gas emitted by each boiler with a turbine; delivering fluid from the superheater unit to the turbine; and delivering fluid from turbine to the reheater unit.
 36. A method as set forth in claim 34, further comprising: delivering fluid from the reheater unit to a turbine; expanding fluid delivered from the reheater with the turbine; and delivering fluid from the turbine to heat exchanger.
 37. A method as set forth in claim 28, further comprising: separating oxygen from air; and delivered the separated oxygen to the upstream boiler for use as the oxidizer.
 38. A method as set forth in claim 28, further comprising filtering flue gas emitted by the downstream boiler to separate fly ash from the flue gas.
 39. A method as set forth in claim 28, further comprising cooling flue gas emitted by the downstream boiler.
 40. A method as set forth in claim 28, further comprising scrubbing flue gas emitted by the downstream boiler to remove sulphur oxides from the flue gas.
 41. A method as set forth in claim 28, wherein each of the steps of burning the oxidizer and carbon-containing fuel comprises pressurizing the respective boiler. 